TY - JOUR
T1 - Technology Overview of Fast Pyrolysis of Lignin
T2 - Current State and Potential for Scale-Up
AU - Singh-Morgan, Amrita
AU - Puente-Urbina, Allen
AU - van Bokhoven, Jeroen A.
N1 - Publisher Copyright:
© 2022 The Authors. ChemSusChem published by Wiley-VCH GmbH.
PY - 2022/7/21
Y1 - 2022/7/21
N2 - Lignin is an abundant natural polymer obtained from lignocellulosic biomass and rich in aromatic substructures. When efficiently depolymerized, it has great potential in the production of value-added chemicals. Fast pyrolysis is a promising depolymerization method, but current studies focus mainly on small quantities of lignin. In this Review, to determine the potential for upscaling, systems used in the most relevant unit operations of fast pyrolysis of lignin are evaluated. Fluidized-bed reactors have the most potential. It would be beneficial to combine them with the following: slug injectors for feeding, hot particle filters, cyclones, and fractional condensation for product separation and recovery. Moreover, upgrading lignin pyrolysis oil would allow the necessary quality parameters for particular applications to be reached.
AB - Lignin is an abundant natural polymer obtained from lignocellulosic biomass and rich in aromatic substructures. When efficiently depolymerized, it has great potential in the production of value-added chemicals. Fast pyrolysis is a promising depolymerization method, but current studies focus mainly on small quantities of lignin. In this Review, to determine the potential for upscaling, systems used in the most relevant unit operations of fast pyrolysis of lignin are evaluated. Fluidized-bed reactors have the most potential. It would be beneficial to combine them with the following: slug injectors for feeding, hot particle filters, cyclones, and fractional condensation for product separation and recovery. Moreover, upgrading lignin pyrolysis oil would allow the necessary quality parameters for particular applications to be reached.
KW - biomass
KW - biorefinery
KW - fast pyrolysis
KW - lignin
KW - sustainable chemistry
UR - http://www.scopus.com/inward/record.url?scp=85130216811&partnerID=8YFLogxK
U2 - 10.1002/cssc.202200343
DO - 10.1002/cssc.202200343
M3 - Artículo de revisión
C2 - 35474609
AN - SCOPUS:85130216811
SN - 1864-5631
VL - 15
JO - ChemSusChem
JF - ChemSusChem
IS - 14
M1 - e202200343
ER -